1202039-13-1

Basic information

• Product Name: methyl (3S,4E,αR)-3-[N-allyl-N-(α-methylbenzyl)amino]hex-4-enoate
• Synonyms: methyl (3S,4E,αR)-3-[N-allyl-N-(α-methylbenzyl)amino]hex-4-enoate
• CAS NO: 1202039-13-1
• Molecular Weight: 287.402
• Mol File: 1202039-13-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl (3S,4E,αR)-3-[N-allyl-N-(α-methylbenzyl)amino]hex-4-enoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (3S,4E,αR)-3-[N-allyl-N-(α-methylbenzyl)amino]hex-4-enoate(1202039-13-1)
• EPA Substance Registry System: methyl (3S,4E,αR)-3-[N-allyl-N-(α-methylbenzyl)amino]hex-4-enoate(1202039-13-1)

Safety Data

• Hazardous Substances Data: 1202039-13-1(Hazardous Substances Data)

Upstream product

• 689-89-4 (2E,4E)-methylhexa-2,4-dienoate 
• 126275-19-2 (R)-N-allyl (1-phenylethyl)amine 

Downstream Products

• 1202039-14-2 methyl (2'S,αR)-2-[N(1')-(α-methylbenzyl)-2',5'-dihydro-1H-pyrrol-2'-yl]ethanoate 

Relevant articles and documents

Asymmetric synthesis of Sedum alkaloids via lithium amide conjugate addition

Conjugate addition of lithium (R)-N-allyl-N-(α-methylbenzyl)amide or lithium (R)-N-but-3-enyl-N-(α-methylbenzyl)amide to an alkyl hexa-2,4-dienoate or alkyl hepta-2,6-dienoate, followed by ring-closing metathesis of the olefin functionalities within the resultant β-amino ester, generates a range of diastereoisomerically pure azacycles in good yield. These homochiral templates are readily transformed to a range of piperidine alkaloids of the Sedum family, and the corresponding five-, seven- and eight-membered ring homologues.