1204324-78-6Relevant articles and documents
Total synthesis of (-)-amathaspiramide F
Sakaguchi, Kazuhiko,Ayabe, Miki,Watanabe, Yusuke,Okada, Takuya,Kawamura, Kazushige,Shinada, Tetsuro,Ohfune, Yasufumi
experimental part, p. 10355 - 10364 (2010/03/03)
The stereoselective total synthesis of the marine alkaloid, (-)-amathaspiramide F (1), was achieved from the α-hydroxy-α-ethynylsilane 2. The key steps involved in the synthesis were (1) the enolate Claisen rearrangement of the α-acyloxy-α-alkenylsilane f