1204482-75-6

Basic information

• Product Name: 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene*GeH₂*BH₃
• Synonyms: 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene*GeH₂*BH₃
• CAS NO: 1204482-75-6
• Molecular Weight: 477.037
• Mol File: 1204482-75-6.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene*GeH₂*BH₃(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene*GeH₂*BH₃(1204482-75-6)
• EPA Substance Registry System: 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene*GeH₂*BH₃(1204482-75-6)

Safety Data

• Hazardous Substances Data: 1204482-75-6(Hazardous Substances Data)

Upstream product

• 1204482-74-5 GeCl₂(1,3-bis(2,6-diisopropylphenyl)imidazole-2-ylidene) 

Relevant articles and documents

Stable complexes of parent digermene: An inorganic analogue of ethylene

The elusive parent inorganic ethylene H2GeGeH2 has been isolated in the form of a stable complex for the first time via donor-acceptor coordination with suitable Lewis base/acid combinations (LB·H2Ge-GeH2·LA; LB = N-heterocyclic carbene or N-heterocyclic olefin; LA = W(CO)5). The nature of the bonding in these species was investigated by density functional theory calculations and revealed the presence of polarized Ge-Ge covalent σ-bonds within the H2Ge-GeH2 arrays and dative Ge-C interactions between the digermene and the carbon-based Lewis bases.

Controlled growth of dichlorogermanium oligomers from lewis basic hosts

To branch or not to branch: A mild stepwise route to various linear and branched (GeCl2)x oligogermylenes supported by Lewis bases is reported, including the carbene-bound Ge4 complex NHC×GeCl2Ge(GeCl3)2 (see picture). Dipp=2,6-iPr2C6H3, NHC=N-heterocyclic carbene. Copyright