120454-65-1Relevant articles and documents
STEREOCHEMICAL EFFECTS OF TRIMETHYLSILYL CHLORIDE (TMSCl) ON THE CONJUGATE ADDITION OF ORGANOCOPPER REAGENTS
Alexakis, A.,Sedrani, R.,Mangeney, P.
, p. 345 - 348 (2007/10/02)
The stereochemical course of the conjugate addition of organocopper reagents, in the presence of TMSCl, is not affected by remote chelation effects, whereas on its absence, the latter may predominate.By this way, it is possible to distinguish the relative