1205666-47-2

Basic information

• Product Name: (S)-1-[(R)-4-benzyl-2-thioxothiazolidin-3-yl]-3-hydroxypent-4-en-1-one
• Synonyms: (S)-1-[(R)-4-benzyl-2-thioxothiazolidin-3-yl]-3-hydroxypent-4-en-1-one
• CAS NO: 1205666-47-2
• Molecular Weight: 307.437
• Mol File: 1205666-47-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (S)-1-[(R)-4-benzyl-2-thioxothiazolidin-3-yl]-3-hydroxypent-4-en-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-1-[(R)-4-benzyl-2-thioxothiazolidin-3-yl]-3-hydroxypent-4-en-1-one(1205666-47-2)
• EPA Substance Registry System: (S)-1-[(R)-4-benzyl-2-thioxothiazolidin-3-yl]-3-hydroxypent-4-en-1-one(1205666-47-2)

Safety Data

• Hazardous Substances Data: 1205666-47-2(Hazardous Substances Data)

Upstream product

• 110199-17-2 (R)-4-benzyl-thiazolidine-2-thione 
• 911040-42-1 1-[(4R)-4-benzyl-2-thioxo-1,3-thiazolidin-3-yl]ethanone 
• 107-02-8 acrolein 

Downstream Products

• 1383331-13-2 (S)-1-[(R)-4-benzyl-2-thioxothiazolidin-3-yl]-3-(tert-butyldimethylsilyloxy)pent-4-en-1-one 

Relevant articles and documents

Stereoselective total synthesis of stagonolide-C

The highly stereoselective synthesis of a biologically active stagonolide-C has been described. The pivotal functionalities are derived from Barbier allylation, an epoxidation by m-CPBA, a chiral-auxiliary mediated acetate aldol addition, a 1,3-anti-reduction, a Sharpless kinetic resolution, a Yamaguchi macrolactonization, and ring-closing metathesis.