1206515-44-7Relevant articles and documents
Cooperative Indium(III)/Silver(I) System for Oxidative Coupling/Annulation of 1,3-Dicarbonyls and Styrenes: Construction of Five-Membered Heterocycles
Ko, Tae Yun,Youn, So Won
, p. 1934 - 1941 (2016)
A cooperative indium(III)/silver(I) system for the synthesis of various five-membered heterocycles, including dihydrofurans, pyrroles, spirolactones, and spiroiminolactones, through the sequential oxidative coupling/annulation reaction of 1,3-dicarbonyl compounds with styrenes has been developed. Four different heterocyclic systems were successfully synthesized depending on the substitution pattern of the substrates using readily available starting materials. This system has the advantages of a broad substrate scope, moderate to good chemical yields, an operationally easy and simple procedure, and short reaction times. (Figure presented.) .
Solvent-dependent oxidative coupling of 1-aryl-1,3-dicarbonyls and styrene
Casey, Brian M.,Eakin, Cynthia A.,Jiao, Jingliang,Sadasivam, Dhandapani V.,Flowers II, Robert A.
experimental part, p. 10762 - 10768 (2010/02/28)
This report describes the scope and mechanism of the solvent-dependent, chemoselective oxidative coupling of 1-aryl-1,3-dicarbonyls with styrene using Ce(IV) reagents. Dihydrofuran derivatives are obtained when reactions are performed in methanol whereas