120708-21-6Relevant articles and documents
Asymmetric 1,4-reductions of and 1,4-additions to enoates and related systems
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, (2008/06/13)
One aspect of the present invention relates to methods for the transition-metal-catalyzed asymmetric 1,4-addition of a nucleophile, e.g., hydride, to cyclic and acyclic enoates and enones. In certain embodiments of the methods of the present invention, th
Lipase-mediated diastereoselective and enantioselective acetylations of 3-substituted cyclohexanols
Tanikaga, Rikuhei,Morita, Akira
, p. 635 - 638 (2007/10/03)
Lipase-mediated acetylation of four diastereomeric and enantiomeric isomers of 3-substituted cyclohexanols 2 has led to an efficient resolution to provide a single stereoisomer, (1R,3S)-cyclohexyl acetate (1R,3S)-3 in a high enantiomeric excess.