120763-13-5 Usage
Description
NiCl2(bathocuproine) is a chemical compound consisting of nickel (Ni), chlorine (Cl), and bathocuproine. It is recognized for its capability to form stable complex structures with other molecules, which makes it a valuable tool for studying chemical reactions and molecular interactions. NiCl2(bathocuproine) also exhibits unique optical and electronic properties, making it suitable for various applications in catalysis, materials science, nanotechnology, polymer production, and organic synthesis.
Uses
Used in Catalysis:
NiCl2(bathocuproine) is used as a catalyst in various chemical reactions, enhancing the reaction rates and improving the overall efficiency of the processes.
Used in Materials Science:
In the field of materials science, NiCl2(bathocuproine) is utilized for its unique properties to develop new materials with specific characteristics, such as improved strength, durability, or conductivity.
Used in Nanotechnology:
NiCl2(bathocuproine) is employed in nanotechnology applications, where its ability to form stable complexes can be used to create nanostructures with tailored properties for various purposes.
Used in Polymer Production:
NiCl2(bathocuproine) is used in the production of certain types of polymers, contributing to the development of new materials with specific properties for different industries.
Used in Organic Synthesis:
As a catalyst in organic synthesis, NiCl2(bathocuproine) aids in the formation of desired organic compounds, making the synthesis process more efficient and effective.
Used in Solar Energy Conversion:
NiCl2(bathocuproine) has been studied for its potential use in solar energy conversion due to its unique optical and electronic properties, which could contribute to the development of more efficient solar energy systems.
Used in Electronic Device Fabrication:
NiCl2(bathocuproine)'s unique properties also make it a candidate for use in the fabrication of electronic devices, where it could improve the performance and functionality of these devices.
Check Digit Verification of cas no
The CAS Registry Mumber 120763-13-5 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,2,0,7,6 and 3 respectively; the second part has 2 digits, 1 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 120763-13:
(8*1)+(7*2)+(6*0)+(5*7)+(4*6)+(3*3)+(2*1)+(1*3)=95
95 % 10 = 5
So 120763-13-5 is a valid CAS Registry Number.
120763-13-5Relevant articles and documents
Reductive Alkylation of Alkenyl Acetates with Alkyl Bromides by Nickel Catalysis
Bai, Yunfei,Han, Guan-Yu,He, Rong-De,Liu, Xue-Yuan,Pan, Xiaobo,Pang, Xiaobo,Shu, Xing-Zhong,Zhao, Zhen-Zhen
supporting information, (2021/12/14)
Catalytic alkylation of stable alkenyl C?O electrophiles is synthetically appealing, but studies to date have typically focused on the reactions with alkyl Grignard reagents. We report herein a cross-electrophile reaction of alkenyl acetates with alkyl bromides. This work has enabled a new method for the synthesis of aliphatic alkenes from alkenyl acetates to be established that can be used to add more structural complexity and molecular diversity with enhanced functionality tolerance. The method allows for a gram-scale reaction and modification of biologically active molecules, and it affords access to useful building blocks. Preliminary mechanistic studies reveal that the NiI species plays an essential role for the success of the coupling of these two reactivity-mismatched electrophiles.
Two-electron HCl to H2 photocycle promoted by Ni(II) polypyridyl halide complexes
Powers, David C.,Anderson, Bryce L.,Nocera, Daniel G.
, p. 18876 - 18883 (2014/01/06)
Photochemical HX splitting requires the management of two protons and the execution of multielectron photoreactions. Herein, we report a photoinduced two-electron reduction of a polypyridyl Ni(II) chloride complex that provides a route to H2 evolution from HCl. The excited states of Ni complexes are too short to participate directly in HX activation, and hence, the excited state of a photoredox mediator is exploited for the activation of HX at the Ni(II) center. Nanosecond transient absorption (TA) spectroscopy has revealed that the excited state of the polypyridine results in a photoreduced radical that is capable of mediating HX activation by producing a Ni(I) center by halogen-atom abstraction. Disproportionation of the photogenerated Ni(I) intermediate affords Ni(II) and Ni(0) complexes. The Ni(0) center is capable of reacting with HX to produce H2 and the polypyridyl Ni(II) dichloride, closing the photocycle for H2 generation from HCl.
