12089-29-1

Basic information

• Product Name: Chromium(1+), bis(h6-benzene)-, iodide (1:1)
• Synonyms: Bis(benzene)chromiumiodide (6CI,7CI); Chromium(1+), bis(benzene)-, iodide (8CI); Chromium(1+), bis(h6-benzene)-, iodide (9CI); Benzene, chromium complex; Bis(benzene)chromium(1+) iodide; Chromium,bis(benzene)iodo-; Dibenzenechromium iodide
• CAS NO: 12089-29-1
• Molecular Formula: C₁₂H₁₂Cr*I
• Molecular Weight: 335.14
• Mol File: 12089-29-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Chromium(1+), bis(h6-benzene)-, iodide (1:1)(CAS DataBase Reference)
• NIST Chemistry Reference: Chromium(1+), bis(h6-benzene)-, iodide (1:1)(12089-29-1)
• EPA Substance Registry System: Chromium(1+), bis(h6-benzene)-, iodide (1:1)(12089-29-1)

Safety Data

• Safety Statements: −." target="_blank">Poison by intravenous route. When heated to decomposition it emits toxic fumes of Cr and I−.:
• Hazardous Substances Data: 12089-29-1(Hazardous Substances Data)

Upstream product

• 12298-68-9 potassium triiodide 
• 1271-54-1 bis(benzene)chromium⁽⁰⁾ 
• 12099-15-9 bis(η6-diphenyl)chromium(0) 
• 14221-02-4 tetrakis(triphenylphosphine)platinum 

Downstream Products

• 1271-54-1 bis(benzene)chromium⁽⁰⁾ 

Relevant articles and documents

Reactivity of germylmercurate complexes

The selective insertion of sulfur into the Ge-Hg bond in the ionic complex 3Hg>-Cp2CO+ results in the formation of mono-, di- and trithiolate derivatives.The compounds have been characterized by elementary analysis, IR, 19F and 199Hg NMR spectroscopy.The molecular structure of 3>--Cp2Co+ has been determined by X-ray analysis.Sulfur-containing complexes are donors of chalcogen atoms in the reactions with covalent and ionic polynuclear organometallic compounds.Ytterbium dicyclopentadienide and vanadocene displace cobaltocene from 2HgI>-Cp2Co+, and Cp2Co removes thallium from its germylmercurate complex.A general scheme for the reaction of vanadocene with cobalticinium germylmercurate has been proposed.The zerovalent triphenylphosphine complex of platinum Pt(PPh3)4 destroys the ionic structure of 2HgI>-(C6H6)2Cr+ to give dibenzenechromium iodide and a polinuclear compound with Ge-Hg-Pt-Ge chain.