12099-17-1

Basic information

• Product Name: Chromium(1+),bis[(1,2,3,4,5,6-h)-1,1'-biphenyl]-,iodide (9CI)
• Synonyms: Bis(biphenyl)chromiumiodide (7CI); Bis(biphenyl)chromium(I) iodide (6CI); Chromium(1+), bis(biphenyl)-,iodide (8CI); 1,1'-Biphenyl, chromium complex; Bis(biphenyl)chromium(1+)iodide; Chromium(I), bis(biphenyl)-, iodide
• CAS NO: 12099-17-1
• Molecular Formula: C24H20 Cr . I
• Molecular Weight: 487.323
• Mol File: 12099-17-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Chromium(1+),bis[(1,2,3,4,5,6-h)-1,1'-biphenyl]-,iodide (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Chromium(1+),bis[(1,2,3,4,5,6-h)-1,1'-biphenyl]-,iodide (9CI)(12099-17-1)
• EPA Substance Registry System: Chromium(1+),bis[(1,2,3,4,5,6-h)-1,1'-biphenyl]-,iodide (9CI)(12099-17-1)

Safety Data

• Hazardous Substances Data: 12099-17-1(Hazardous Substances Data)

Upstream product

• 60-29-7 diethyl ether 
• 12298-68-9 potassium triiodide 
• 12095-46-4 [(η6-Ph₂)(η6-PhH)Cr] 
• 1271-54-1 bis(benzene)chromium⁽⁰⁾ 
• 12099-15-9 bis(η6-diphenyl)chromium(0) 
• 92-52-4 biphenyl 
• 14362-44-8 iodide 
• 10025-73-7 chromium(III) chloride 
• 100-58-3 phenylmagnesium bromide 
• 7681-11-0 potassium iodide 
• 7429-90-5 aluminium 
• 7439-93-2 lithium 
• 33409-77-7 {(C₆H₅C₆H₅)2Cr}⁽¹⁺⁾*OC₆H₅^(1-)={(C₆H₅C₆H₅)2Cr}OC₆H₅ 
• 12298-68-9 potassium triiodide 

Downstream Products

• 12099-15-9 bis(η6-diphenyl)chromium(0) 
• 74858-56-3 bis(biphenyl)chromium(I) tetraphenylborate 
• 92-52-4 biphenyl 
• 98345-56-3 (H₅C₂C₆H₅)2Cr⁽¹⁺⁾*I^(1-)*HCCl₃=(H₅C₂C₆H₅)2CrI*HCCl₃ 

Relevant articles and documents

ELECTROCHEMICAL AND ESR KINETICS STUDIES OF ELECTRON TRANSFER IN THE SYSTEM BIS(η6-ARENE)CHROMIUM(0)/BIS(η6-ARENE)CHROMIUM(I)

The self-exchange rates and activation parameters in the (η6-arene2Cr0/(η6-arene)2CrI systems (where arene = toluene, benzene, methoxylbenzene, biphenyl, ethylbenzoate and chlorobenzene) have been measured by the ESR line broadening technique in DMSO solvent.The one-electron reduction was investigated by cyclic voltammetry for the series of substituted complexes of (η6-arene)2CrI.A linear correlation was obtained between the measured E1/2 values and the sum of Hammett parameters, Σ?m.For a series of solvents, a linear relationship between log k (the exchange rate constant of (biph)2Cr0/+1) and (1/n2-1/Ds) where n2 and Ds are the optical and static dielectric constants of the solvent medium, respectively, has been observed.This linearity is predicted by Marcus treatment for outer-sphere electron transfer process.A correlation of the oxidation stability of sandwich compounds with their gas-phase ionization potentials is evident from a linear relationship between the oxidation half-potentials E1/2 (or sum of Hammett Σ?m values) and the gas-phase ionization potentials.