12099-72-8

Basic information

• Product Name: mer-(PMe₂Ph)3H-trans-Cl₂Ir(III)
• CAS NO: 12099-72-8
• Molecular Weight: 678.581
• Mol File: 12099-72-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: mer-(PMe₂Ph)3H-trans-Cl₂Ir(III)(CAS DataBase Reference)
• NIST Chemistry Reference: mer-(PMe₂Ph)3H-trans-Cl₂Ir(III)(12099-72-8)
• EPA Substance Registry System: mer-(PMe₂Ph)3H-trans-Cl₂Ir(III)(12099-72-8)

Safety Data

• Hazardous Substances Data: 12099-72-8(Hazardous Substances Data)

Upstream product

• 15613-31-7 mer-IrCl₃(PMe₂Ph)3 
• 992-98-3 thallium formate 
• 4039-32-1 lithium hexamethyldisilazane 

Downstream Products

• 21919-29-9 fac-trichlorotris[dimethyl(phenyl)phosphine]iridium(III) 
• 92842-97-2 Rh(P(C₆H₅)2CH₂CH₂P(C₆H₅)2)HClIrCl(P(C₆H₅)(CH₃)2)3⁽¹⁺⁾*BF₄^(1-)=Rh(P(C₆H₅)2CH₂CH₂P(C₆H₅)2)HClIrCl(P(CH₃)2C₆H₅)3BF₄ 

Relevant articles and documents

MODIFICATION OF THE ACID-BASE PROPERTIES OF HYDROXYCARBONYL COMPLEXES OF IRIDIUM(III) BY SUBSTITUTION OF CARBON MONOXIDE BY A TERTIARY PHOSPHINE LIGAND

A dichloromethane solution of the cationic carbonyl complex (IrCl2(CO)(PMe2Ph)3)(ClO4) reacts with aqueous KOH to give (IrCl2(CO2H)(PMe2Ph)3) which has been characterised spectroscopically.This CO2H compound is very much more basic and very much less acidic than (IrCl2(CO2H)(CO)(PMe2Ph)2).Tertiary amines will not deprotonate (IrCl2(CO2H)(PMe2Ph)3) while Li(N(SiMe3)2) leads to decarboxylation products trans, mer- and cis, mer-(IrHCl2(PMe2Ph)3).The mechanisms of these reactions are considered and the hydroxycarbonyl complex is compared with its formato isomer which decarboxylates much less readily.