120999-45-3Relevant articles and documents
Palladium catalyzed reactions of α-bromo-α,β-unsaturated carbonyl compounds with 1-(E)-alkenylboronic acids
Urdaneta, Neudo,Ruiz, Jacqueline,Zapata, Antonio J.
, p. C33 - C34 (1994)
A new synthesis of functionalized 1,3-dienes is described based on the palladium catalyzed coupling reaction of 1-(E)-alkenylboronic acids with α-bromo-α,β-unsaturated carbonyl compounds. Key words: Palladium; Alkenyl; Boronic acid; Catalysis
HYDROFORMYLATION AND HYDROCARBONYLATION OF ENYMES BY RHODIUM CARBONYL CLUSTER: A NEW ROUTE TO CYCLIC ENONES
Doyama, Kazuo,Joh, Takashi,Takahashi, Shigetoshi
, p. 4497 - 4500 (2007/10/02)
The reaction of but-1-en-3-yne derivates with carbon monoxide and hydrogen in the presence of Rh4(CO)12 catalyst gave formyl-dienes, cyclopentenones and unsaturated lactones, which shows the CC is much more reactive than the C=C moiety and may provide