1210066-82-2Relevant articles and documents
Palladium-catalyzed allylic acyloxylation of terminal alkenes in the presence of a base
Thiery, Emilie,Aouf, Chahinez,Belloy, Julien,Harakat, Dominique,Bras, Jean Le,Muzart, Jacques
experimental part, p. 1771 - 1774 (2010/05/01)
"Chemical Equation Presentation" The efficiency and the selectivity of the Pd-catalyzed oxidation, in carboxylic acids, of terminal alkenes are strongly improved in the presence of a base. The methodology is particularly well adapted for the oxidation of homoallylic alcohols, for which the resulting acyloxylated products are obtained selectively as E-isomers in fair to good yields. 2010 American Chemical Society.