121077-49-4

Basic information

• Product Name: 5-cyclohexyl-2,4-pentadienal
• CAS NO: 121077-49-4
• Molecular Weight: 164.247
• Mol File: 121077-49-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 5-cyclohexyl-2,4-pentadienal(CAS DataBase Reference)
• NIST Chemistry Reference: 5-cyclohexyl-2,4-pentadienal(121077-49-4)
• EPA Substance Registry System: 5-cyclohexyl-2,4-pentadienal(121077-49-4)

Safety Data

• Hazardous Substances Data: 121077-49-4(Hazardous Substances Data)

Upstream product

• 110905-37-8 (E)-(4-Oxo-2-butenyl)phosphonsaeure-diethylester 
• 2043-61-0 cyclohexanecarbaldehyde 
• 129422-73-7 (5-aza-5-cyclohexylpenta-2,4-dienyl)diethoxyphosphin-1-one 
• 2798-73-4 (Z)-1-methoxybut-1-en-3-yne 

Relevant articles and documents

AgAsF6 as safe alternative to AgClO4 for generating cationic zirconocene species: Utilities in Lewis acid-promoted selective C---C bond forming reactions

For generating cationic zirconocene species that are useful for organic synthesis, AgAsF6 proved to be an efficient catalyst that serves as a safe alternative to AgClO4. Scope and limitation is discussed on this new catalyst in the processes including (1) alkyl/alkenyl transfer reaction from organozirconocene chloride to aldehyde, (2) two- and four-carbon homologation of aldehyde, (3) dual synthetic methods of 1,3-dienes from aldehydes/ketones via 1,3-bimetallic species, and (4) three-component alkylative cycloaddition via o-quinodimethane species.

Synthesis of polyconjugated aldehydes using a new Horner--Wadsworth--Emmons reagent.

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