12110-35-9

Basic information

• Product Name: Iron, dicarbonyl(h5-2,4-cyclopentadien-1-yl)(2,3,5,6-tetrafluorophenyl)-
• Synonyms: Iron,dicarbonyl-p-cyclopentadienyl(2,3,5,6-tetrafluorophenyl)-(8CI); Iron, dicarbonylcyclopentadienyl(2,3,5,6-tetrafluorophenyl)- (7CI); NSC120053
• CAS NO: 12110-35-9
• Molecular Formula: C13H6 F4 Fe O2
• Molecular Weight: 326.03
• Mol File: 12110-35-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Iron, dicarbonyl(h5-2,4-cyclopentadien-1-yl)(2,3,5,6-tetrafluorophenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Iron, dicarbonyl(h5-2,4-cyclopentadien-1-yl)(2,3,5,6-tetrafluorophenyl)-(12110-35-9)
• EPA Substance Registry System: Iron, dicarbonyl(h5-2,4-cyclopentadien-1-yl)(2,3,5,6-tetrafluorophenyl)-(12110-35-9)

Safety Data

• Hazardous Substances Data: 12110-35-9(Hazardous Substances Data)

Upstream product

• 344-04-7 bromopentafluorobenzene 
• 344-07-0 1-chloro-2,3,4,5,6-pentafluorobenzene 
• 827-15-6 1,2,3,4,5-pentafluoro-6-iodobenzene 

Relevant articles and documents

Halophilic reactions of pentafluorohalobenzenes with transition-metal carbonyl anions

In the present work we widen the scope of the halophilic mechanism of nucleophilic aromatic substitution, which we found earlier for the reaction of pentafluorochlorobenzene with [CpFe(CO)2]- anion, to reactions of pentafluorohalobenzenes (Hal=Cl, Br, I) with various metal carbonyl anions [Re(CO)5]-, [Mn(CO)5]- and [CpFe(CO)2]-. Nucleophilic aromatic substitution with the [CpFe(CO)2]- anion yields C6F5Fe(CO)2Cp, while with [Re(CO)5]- and [Mn(CO)5]- anions the halo(acyl)metallates cis-[C6F5(CO)M(CO)4Hal]Na (M=Mn, Re) are obtained.