12112-97-9

Basic information

• Product Name: [Fe(CO)3(η-N(C6H5)=CH-CH=CHPh)]
• CAS NO: 12112-97-9
• Molecular Weight: 347.153
• Mol File: 12112-97-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: [Fe(CO)3(η-N(C6H5)=CH-CH=CHPh)](CAS DataBase Reference)
• NIST Chemistry Reference: [Fe(CO)3(η-N(C6H5)=CH-CH=CHPh)](12112-97-9)
• EPA Substance Registry System: [Fe(CO)3(η-N(C6H5)=CH-CH=CHPh)](12112-97-9)

Safety Data

• Hazardous Substances Data: 12112-97-9(Hazardous Substances Data)

Upstream product

• 866123-02-6 (η2-PhCH=CHCHO)Fe(CO)4 
• 73979-12-1 triphenylstibine-dicarbonyl(1-2-η:3-4-η-1,4-diphenyl-1-azabuta-1,3-diene)iron 
• 73979-11-0 triphenylarsine-dicarbonyl(1-2-η:3-4-η-1,4-diphenyl-1-azabuta-1,3-diene)iron 
• 12119-27-6 triphenylphosphine-dicarbonyl(1-2-η:3-4-η-1,4-diphenyl-1-azabuta-1,3-diene)iron 

Downstream Products

• 110796-12-8 {(η4-styrene)CH(m-CH3C6H4)N(C6H5)ethoxycarbene}iron(carbonyl)2 
• 110796-14-0 {(η4-styrene)CH(p-CF3C6H4)N(C6H5)ethoxycarbene}iron(carbonyl)2 
• 12152-72-6 (cyclohexa-1,3-diene)iron tricarbonyl 
• 14741-34-5 tricarbonyl bis(triphenylphosphine) iron 
• 12119-27-6 triphenylphosphine-dicarbonyl(1-2-η:3-4-η-1,4-diphenyl-1-azabuta-1,3-diene)iron 
• 38894-55-2 1,2-bis(diphenylphosphino)ethaneiron(0) tricarbonyl 
• 61300-46-7 Fe(CO)2((P(C₆H₅)2CH₂)2)2 
• 20516-72-7 (As(C₆H₅)3)2Fe(CO)3 
• 73979-11-0 triphenylarsine-dicarbonyl(1-2-η:3-4-η-1,4-diphenyl-1-azabuta-1,3-diene)iron 
• 14375-86-1 (Sb(C₆H₅)3)2Fe(CO)3 
• 73979-12-1 triphenylstibine-dicarbonyl(1-2-η:3-4-η-1,4-diphenyl-1-azabuta-1,3-diene)iron 
• 38720-29-5 tricarbonyl[(1-4-η)-1-(4-methoxyphenyl)-4-phenyl-1-azabuta-1,3-diene]iron 
• 13463-40-6 iron pentacarbonyl 
• 110796-11-7 {(η4-styrene)CH(C6H5)N(C6H5)ethoxycarbene}iron(carbonyl)2 

Relevant articles and documents

Mechanism and Equilibrium Constants of the Reaction between Carbon Monoxide and Triphenyl-phosphine-, -arsine-, and -stibine-dicarbonyl-(1-2-η:3-4-η-1,4-diphenyl-1-azabuta-1,3-diene)iron

Equilibrium and rate data have been measured for the ligand-substitution rection 4-C6H5CH=ChCh=NC6H5)-(CO)2L> + CO = 4-C6H5CH=CHCH=NC6H5)(CO)3> + L where L=PPh3, AsPh3, or SbPh3.The reaction proceeds via a dissociative equilibrium of the η4 complexes to ? unsaturated complexes.Variations of the equlibrium and rate constants appear to be mainly associated with the basicity of the ligands.

A new method for the synthesis of iron azadiene and diene complexes. Reaction of (η2-RCHCHCOR')Fe(CO)4 with aniline and ylide

The reactions of (η2-RCH=CHCOR')Fe(CO)4 (R = Ph, R' = H; R = H, R' = H and R = H, R' = CH3) with aniline or its derivative afforded η4-azadiene complexes 1, 2 and 3 in various yields.The azadiene ligands in 2 and 3 are too reactive to isolate at ambient temperature, but 2 and 3 are stable up to ca 110 deg C.Treatment of (ν2-CH2=CHCHO)Fe(CO)4 with Ph3PCHOOMe gave a η2-diene complex 4 which was converted to (η4-CH=CHCH=CHCOOMe)Fe(CO)3 on heating, or reacting with (CH3)3NO.