121198-70-7Relevant articles and documents
GENERATION OF ESTER AND AMIDE DERIVATIVES OF METHAPHOSPHORIC ACID BY PHOTOLYSIS OF 2,3-OXAPHOSPHABICYCLOOCT-5-ENE DERIVATIVES
Quin, Louis D.,Pete, Bela,Szewczik, Jerzy,Hughes, Alan N.
, p. 2627 - 2630 (1988)
Irradiation at 254 nm of P-NMe2 and P-OEt derivatives of phosphonates where P is incorporated into the 2,3-oxabicyclooct-ene framework results in fragmentation of the molecules to release N,N-dimethylamino metaphosphoramidate and ethyl metaphophate, respectively.Both species polymerize rapidly, but are effectively trapped as phosphate derivatives when alcohols are included in the reaction mixtures.