121321-59-3

Basic information

• Product Name: tricarbonyl(4-methoxy-1-phenoxybenzene)chromium⁽⁰⁾
• CAS NO: 121321-59-3
• Molecular Weight: 336.264
• Mol File: 121321-59-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: tricarbonyl(4-methoxy-1-phenoxybenzene)chromium⁽⁰⁾(CAS DataBase Reference)
• NIST Chemistry Reference: tricarbonyl(4-methoxy-1-phenoxybenzene)chromium⁽⁰⁾(121321-59-3)
• EPA Substance Registry System: tricarbonyl(4-methoxy-1-phenoxybenzene)chromium⁽⁰⁾(121321-59-3)

Safety Data

• Hazardous Substances Data: 121321-59-3(Hazardous Substances Data)

Upstream product

• 56213-59-3 η6-(4-methoxyfluorobenzene)tricarbonylchromium(0) 
• 139-02-6 sodium phenoxide 
• 86409-62-3 tricarbonyl(1,4-dichlorobenzene)chromium⁽⁰⁾ 

Relevant articles and documents

Reactions of aryloxy anions with organometallic aryl cation equivalents; a route to substituted diphenyl ethers

Tricarbonyl(1,4-dichlorobenzene)chromium(0) and chlorobenzene(cyclopentadienyl)iron(II) hexafluorophosphate undergo nucleophilic substitution with sodium phenoxide to give tricarbonyl(4-chloro-1-phenoxybenzene)chromium(0) and phenoxybenzene(cyclopentadienyl)iron(II) hexafluorophosphate, respectively.In the former case, the second chlorine is subsequently displaced by methoxide, and this represents a potencially versatile synthsis of substituted diphenyl ethers.Neither of the complexes react with 2,6-dibromo-4-methylphenoxide, but both phenoxides add to substituted tricarbonylcyclohexadienyliumiron complexes to give neutral tricarbonyldieneiron(0) complexes.