121440-73-1

Basic information

• Product Name: carbonic acid 1,1-dimethylethyl 1,3-phenyl-2(E)-propenyl ester
• Synonyms: carbonic acid 1,1-dimethylethyl 1,3-phenyl-2(E)-propenyl ester
• CAS NO: 121440-73-1
• Molecular Weight: 310.393
• Mol File: 121440-73-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: carbonic acid 1,1-dimethylethyl 1,3-phenyl-2(E)-propenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: carbonic acid 1,1-dimethylethyl 1,3-phenyl-2(E)-propenyl ester(121440-73-1)
• EPA Substance Registry System: carbonic acid 1,1-dimethylethyl 1,3-phenyl-2(E)-propenyl ester(121440-73-1)

Safety Data

• Hazardous Substances Data: 121440-73-1(Hazardous Substances Data)

Upstream product

• 14371-10-9 (E)-3-phenylpropenal 
• 24424-99-5 di-tert-butyl dicarbonate 
• 62668-02-4 (E)-1,3-diphenyl-2-propen-1-ol 

Downstream Products

• 121440-88-8 N-Benzyl-N-((E)-(R)-1,3-diphenyl-allyl)-benzamide 
• 14097-24-6 (R)-1,3-diphenylpropanol 
• 941278-46-2 (1''R,4S,2''E)-4-(1'',3''-diphenylprop-2''-enyl)-3-(2'-propenyl)-4-methyl-oxazolidin-2-one 

Relevant articles and documents

General method for the palladium-catalyzed allylation of aliphatic alcohols

A palladium catalysis-mediated approach to coupling aliphatic alcohols with allyl carbonates has been developed. The method allows for the allylation of primary, secondary, and tertiary alcohols efficiently under mild conditions. Limitations were explored as well as the asymmetric application of the chemistry. Regiochemical and olefin geometry was controlled in the coupling of unsymmetrical allylating agents. Transient allyl carbonates were observed in the coupling, which comprised the trans-carboxylation of the allyl-carbonate with the requisite alcohol.