1215002-19-9Relevant articles and documents
Novel dienone-phenol type rearrangement of 4,4-disubstituted cyclohexadienone system using thiosilane
Wada, Yasufumi,Otani, Kouji,Endo, Noriko,Kita, Yasuyuki,Fujioka, Hiromichi
supporting information; experimental part, p. 797 - 799 (2010/06/12)
Thiosilane and a catalytic amount of a Bronsted acid mediate the novel domino-type rearrangement reaction of the 4,4-disubstituted cyclohexadienones to produce the 3,4-disubstituted benzenethioethers; the key step is 1,2-addition of thiosilane to dienone.