121898-20-2

Basic information

• Product Name: (S)-2-Chloro-2,2-difluoro-1-(p-tolylthiomethyl)ethyl hydrogen phthalate
• CAS NO: 121898-20-2
• Molecular Weight: 400.831
• Mol File: 121898-20-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (S)-2-Chloro-2,2-difluoro-1-(p-tolylthiomethyl)ethyl hydrogen phthalate(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-2-Chloro-2,2-difluoro-1-(p-tolylthiomethyl)ethyl hydrogen phthalate(121898-20-2)
• EPA Substance Registry System: (S)-2-Chloro-2,2-difluoro-1-(p-tolylthiomethyl)ethyl hydrogen phthalate(121898-20-2)

Safety Data

• Hazardous Substances Data: 121898-20-2(Hazardous Substances Data)

Upstream product

• 121898-08-6 (S)-1-Chloro-1,1-difluoro-3-((R)-toluene-4-sulfinyl)-propan-2-ol 
• 121898-05-3 1-Chloro-1,1-difluoro-3-((R)-toluene-4-sulfinyl)-propan-2-one 

Downstream Products

• 121898-23-5 (S)-1-Chloro-1,1-difluoro-2-propyl methyl phthalate 

Relevant articles and documents

Homochiral Perfluoroalkyl-Group-Substituted Secondary Alcohols Through Stereoselective Reduction of Perfluoroalkyl 1-(p-Tolylsulfinyl)alkyl Ketones

The reduction of some enantiomerically pure perfluoroalkyl α-(p-tolylsulfinyl) ketones was performed.Alcohols containing perfluoroalkyl and p-tolylsulfinyl groups were obtained with high diastereoselection when a phenyl residue was present on the sulfinylated carbon and with lower diastereoselection in the other cases.Removal of the chiral sulfinyl group from single diastereoisomers gave secondary alcohols containing a perfluoroalkyl group in enantiomerically pure form.