1219468-14-0

Basic information

• Product Name: N-benzoylimino-3,4-dihydro-6-methylisoquinolinium betaine
• Synonyms: N-benzoylimino-3,4-dihydro-6-methylisoquinolinium betaine
• CAS NO: 1219468-14-0
• Molecular Weight: 264.327
• Mol File: 1219468-14-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-benzoylimino-3,4-dihydro-6-methylisoquinolinium betaine(CAS DataBase Reference)
• NIST Chemistry Reference: N-benzoylimino-3,4-dihydro-6-methylisoquinolinium betaine(1219468-14-0)
• EPA Substance Registry System: N-benzoylimino-3,4-dihydro-6-methylisoquinolinium betaine(1219468-14-0)

Safety Data

• Hazardous Substances Data: 1219468-14-0(Hazardous Substances Data)

Upstream product

• 613-94-5 benzoic acid hydrazide 

Downstream Products

• 1621598-75-1 ((1S,2S,10bS)-2-(2-hydroxyethyl)-8-methyl-1-phenyl-1,2,5,6-tetrahydropyrazolo[5,1-a]isoquinolin-3(10bH)-yl)(phenyl)methanone 
• 1427179-26-7 N-(1-(1-(tert-butyl)-1H-tetrazol-5-yl)-6-methyl-3,4-dihydroisoquinolin-2(1H)-yl)benzamide 
• 1357787-17-7 2-methyl-N-(9-methyl-3-phenyl-6,7-dihydro-[1,3,4]oxadiazino[5,4-a]isoquinolin-1(11bH)-ylidene)propan-2-amine 
• 1337924-62-5 C₂₅H₂₂N₂O 
• 1304727-03-4 C₂₃H₂₈N₂O₂ 

Relevant articles and documents

Chiral Phosphoric Acid-Catalyzed Enantioselective Formal [3+2] Cycloaddition of Azomethine Imines with Enecarbamates

The first catalytic asymmetric inverse electron demand 1,3-dipolar cycloaddition of azomethine imines with enecarbamates has been developed. Isoquinoline-fused pyrazolidines containing two or three contiguous stereogenic centers were obtained in high yields with excellent regio-, diastereo-, and enantioselectivities. The pyrazolidine ring can be opened to install an aminal, α-amino nitrile, or homoallylamine function with an excellent control of the newly generated stereogenic center. Access to aminobenzo[a]quinolizidine is also documented. Acid catalysis: The first catalytic asymmetric inverse electron demand 1,3-dipolar cycloaddition of azomethine imines with enecarbamates has been developed. Isoquinoline-fused pyrazolidines containing two or three contiguous stereogenic centers were obtained in high yields with excellent regio-, diastereo-, and enantioselectivities (see scheme).