121958-41-6

Basic information

• Product Name: [(2R,3R)-3-phenyloxiran-2-yl]methyl 4-methylbenzenesulfonate
• Synonyms: [(2R,3R)-3-phenyloxiran-2-yl]methyl 4-methylbenzenesulfonate
• CAS NO: 121958-41-6
• Molecular Weight: 304.367
• Mol File: 121958-41-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: [(2R,3R)-3-phenyloxiran-2-yl]methyl 4-methylbenzenesulfonate(CAS DataBase Reference)
• NIST Chemistry Reference: [(2R,3R)-3-phenyloxiran-2-yl]methyl 4-methylbenzenesulfonate(121958-41-6)
• EPA Substance Registry System: [(2R,3R)-3-phenyloxiran-2-yl]methyl 4-methylbenzenesulfonate(121958-41-6)

Safety Data

• Hazardous Substances Data: 121958-41-6(Hazardous Substances Data)

Upstream product

• 21915-53-7 2,3-epoxy-3-phenyl-1-propanol 
• 98-59-9 p-toluenesulfonyl chloride 
• 104-54-1 3-Phenylpropenol 
• 4407-36-7 (2E)-3-phenyl-2-propen-1-ol 
• 40641-81-4 trans-2,3-epoxy-3-phenylpropan-1-ol 

Downstream Products

• 698-87-3 3-phenyl-2-propanol 
• 104713-12-4 (1S)-1-phenylprop-2-en-1-ol 

Relevant articles and documents

Synthesis of Tetrahydroquinoline-Embedded Bridged Benzothiaoxazepine-1,1-dioxides

A diastereoselective synthesis of previously unknown tetrahydroquinoline-containing bridged benzothiaoxazepine-1,1-dioxides is presented. The three-step protocol uses readily available N-aryl-2-fluorobenzenesulfonamides and trans-2,3-epoxy-cinnamyl-alcohol-derived tosylates as the starting materials, involves N-alkylation of sulfonamides, intramolecular epoxide ring-opening, and SNAr reactions as the reaction steps, and requires only one chromatographic purification to access the desired products in good overall yields.

Synthese optisch aktiver Phosphane via Sharpless-Epoxidierung

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