122-65-6Relevant articles and documents
N,N′-dibenzyldithiooxamide
Bruno, Giuseppe,Lanza, Santo,Nicolo, Francesco,Tresoldi, Giuseppe,Rosace, Giuseppe
, p. o608-o609 (2002)
The title compound, alternatively known as N,N′-dibenzylethanedithioamide, C16H16N2S2, lies about an inversion centre and contains a planar trans-dithiooxamide fragment characterized by a strong intramolecular hydrogen bond between the S atom and the adjacent amide H atom in the solid state, with an S...N distance of 2.926 (1) A. The aryl substituent is oriented orthogonal to the mean plane of the trans-dithiooxamide fragment due to steric hindrance and this effect is discussed.
N,N- und N,N'-disubstituierte Dithiooxalsaeurediamide aus Chloracetonitril, Schwefel und Aminen
Thiel, Wilfried,Viola, Horst,Mayer, Roland
, p. 326 - 327 (2007/10/02)
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Reactions of Cyanodithioformates with Primary Amines
Kibbel, H. U.,Kuecken, M.,Peters, E.,Weber, H.
, p. 41 - 48 (2007/10/02)
N-alkyldithiooxamides 3 and N,N-dialkyldithiooxamides 4 were synthesized in good yields by reaction of cyanodithioformates 1 with primary aliphatic amines.N-alkylcyanodithioformamides 2, intermediates in these reactions were obtained in very low yields only.The reaction of 1 and diaminoethane or 1,3-diaminopropane afforded imidazolidine-2-thione 5a respectively perhydropyrimidine-2-thione 5b.The reaction of 1 with 1-chloro-2-aminoethane did gave 2-thiocarbamoylthiazoline 7.