122045-07-2

Basic information

• Product Name: (E)-4,4′-(diazene-1,2-diyl)dibenzonitrile
• CAS NO: 122045-07-2
• Molecular Weight: 232.244
• Mol File: 122045-07-2.mol
• Article Data: 31

Chemical Properties

• Boiling Point: 464.2±30.0 °C(Predicted)
• Density: 1.13±0.1 g/cm3(Predicted)
• CAS DataBase Reference: (E)-4,4′-(diazene-1,2-diyl)dibenzonitrile(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-4,4′-(diazene-1,2-diyl)dibenzonitrile(122045-07-2)
• EPA Substance Registry System: (E)-4,4′-(diazene-1,2-diyl)dibenzonitrile(122045-07-2)

Safety Data

• Hazardous Substances Data: 122045-07-2(Hazardous Substances Data)

Usage

Description

(E)-4,4′-(diazene-1,2-diyl)dibenzonitrile, a chemical compound with the molecular formula C14H8N4, is a diazene derivative featuring a dibenzonitrile backbone and is classified as a diarylamine. This yellow solid is sparingly soluble in water and is primarily recognized for its role as an intermediate in the synthesis of other organic compounds.

Uses

Used in Pharmaceutical Industry:
(E)-4,4′-(diazene-1,2-diyl)dibenzonitrile is used as a synthetic intermediate for the creation of more complex and functionalized compounds. Its unique chemical structure makes it a potentially useful building block in the development of new pharmaceuticals, contributing to the advancement of drug discovery and design.
Used in Materials Science:
In the field of materials science, (E)-4,4′-(diazene-1,2-diyl)dibenzonitrile is utilized as a precursor for the synthesis of novel materials with specific properties. Its incorporation into these materials can lead to the development of advanced materials with applications in various industries, such as electronics, aerospace, and automotive.

Upstream product

• 31125-07-2 4-cyanonitrosobenzene 
• 873-74-5 4-Aminobenzonitrile 
• 1030-22-4 4,4'-dicyanoazoxybenzene 
• 931-89-5 (E)-cyclooctene 
• 117911-71-4 N-(4-Cyanophenyl)-O-diphenylphosphinoylhydroxylamine 
• 88730-39-6 C₁₀H₁₀N₂O₄S 
• 67-56-1 methanol 
• 18523-41-6 4-azidobenzonitrile 
• 103-71-9 phenyl isocyanate 
• 88046-97-3 4-Phenylsulfanylamino-benzonitrile 
• 109-73-9 N-butylamine 
• 762-42-5 dimethyl acetylenedicarboxylate 
• 121-69-7 N,N-dimethyl-aniline 
• 619-72-7 4-nitrobenzonitrile 

Downstream Products

• 10282-32-3 4-(benzylamino)benzonitrile 
• 21190-30-7 N,N'-bis(4-cyanophenyl)hydrazine 
• 5320-91-2 4,4'-bismethoxycarbonylazobenzene 
• 3646-57-9 bis(4-nitrophenyl)diazene 
• 100723-77-1 2,3,4,9-tetrahydro-1H-carbazole-6-carbonitrile 
• 873-74-5 4-Aminobenzonitrile 
• 115-11-7 isobutene 

Relevant articles and documents

A Molecular Hybrid of an Atomically Precise Silver Nanocluster and Polyoxometalates for H2 Cleavage into Protons and Electrons

Atomically precise silver (Ag) nanoclusters are promising materials as catalysts, photocatalysts, and sensors because of their unique structures and mixed-valence states (Ag+/Ag0). However, their low stability hinders the in-depth st

Electrosynthesis of Azobenzenes Directly from Nitrobenzenes

The electrochemical reduction strategy of nitrobenzenes is developed. The chemistry occurs under ambient conditions. The protocol uses inert electrodes and the solvent, DMSO, plays a dual role as a reducing agent. Its synthetic value has been demonstrated by the highly efficient synthesis of symmetric, unsymmetric and cyclic azo compounds.

Tandem selective reduction of nitroarenes catalyzed by palladium nanoclusters

We report a catalytic tandem reduction of nitroarenes by sodium borohydride (NaBH4) in aqueous solution under ambient conditions, which can selectively produce five categories of nitrogen-containing compounds: anilines, N-aryl hydroxylamines, azoxy-, azo- and hydrazo-compounds. The catalyst is in situ-generated ultrasmall palladium nanoclusters (Pd NCs, diameter of 1.3 ± 0.3 nm) from the reduction of Pd(OAc)2 by NaBH4. These highly active Pd NCs are stabilized by surface-coordinated nitroarenes, which inhibit the further growth and aggregation of Pd NCs. By controlling the concentration of Pd(OAc)2 (0.1-0.5 mol% of nitroarene) and NaBH4, the water/ethanol solvent ratio and the tandem reaction sequence, each of the five categories of N-containing compounds can be obtained with excellent yields (up to 98%) in less than 30 min at room temperature. This tunable catalytic tandem reaction works efficiently with a broad range of nitroarene substrates and offers a green and sustainable method for the rapid and large-scale production of valuable N-containing chemicals.