1220516-06-2Relevant articles and documents
Concurrent α-iodination and N-arylation of cyclic β-enaminones
Chen, Yan,Ju, Tong,Wang, Junwei,Yu, Wenquan,Du, Yunfei,Zhao, Kang
, p. 231 - 234 (2010)
A variety of N-substituted 3-aminocyclohex-2-enones were converted into the corresponding N-arylated α-iodo enaminones in high yields via concurrent N-iodination and N-arylation mediated by ArI(OAc)2. A mechanism is postulated to account for the reaction differences between the cyclic and the acyclic -enaminones, which undergo predominant β-acetoxylation under the same reaction conditions.