122181-86-6

Basic information

• Product Name: 2H-Isoindole-1-carboxylicacid,2-amino-4,5,6,7-tetrahydro-,methylester(9CI)
• Synonyms: 2H-Isoindole-1-carboxylicacid,2-amino-4,5,6,7-tetrahydro-,methylester(9CI)
• CAS NO: 122181-86-6
• Molecular Formula: C₁₀H₁₄N₂O₂
• Molecular Weight: 194.23
• Product Categories: AMINOACID
• Mol File: 122181-86-6.mol
• Article Data: 2

Chemical Properties

• Melting Point: 77-78 °C
• Boiling Point: 397.6±52.0 °C(Predicted)
• Appearance: /
• Density: 1.32±0.1 g/cm3(Predicted)
• PKA: -3.57±0.20(Predicted)
• CAS DataBase Reference: 2H-Isoindole-1-carboxylicacid,2-amino-4,5,6,7-tetrahydro-,methylester(9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 2H-Isoindole-1-carboxylicacid,2-amino-4,5,6,7-tetrahydro-,methylester(9CI)(122181-86-6)
• EPA Substance Registry System: 2H-Isoindole-1-carboxylicacid,2-amino-4,5,6,7-tetrahydro-,methylester(9CI)(122181-86-6)

Safety Data

• Hazardous Substances Data: 122181-86-6(Hazardous Substances Data)

Upstream product

• 122181-84-4 1-carbomethoxy-2-phthalimido-4,5,6,7-tetrahydro-2H-isoindole 
• 15753-50-1 cis-1,2-cyclohexanedimethanol 
• 51555-65-8 cyclohexane-1,2-dicarbaldehyde 
• 122181-81-1 2-phthalimido-4,5,6,7-tetrahydro-2H-isoindole 

Downstream Products

• 6089-09-4 4-pentynoic acid 
• 145072-02-2 2-[(2R,3R)-3-((S)-1-Benzyloxy-ethyl)-2-methyl-pent-4-ynoylamino]-4,5,6,7-tetrahydro-2H-isoindole-1-carboxylic acid methyl ester 
• 145072-06-6 2-[(3R,4R)-3-((S)-1-Benzyloxy-ethyl)-4-methyl-2-methylene-5-oxo-pyrrolidin-1-yl]-4,5,6,7-tetrahydro-2H-isoindole-1-carboxylic acid methyl ester 

Relevant articles and documents

Studies on the Synthesis of Phytochrome and Related Tetrapyrroles. Dihydropyrromethenones by Photochemical Rearrangement of N-Pyrrolo Enamides

Dihydropyrromethenone 67b, a potential precursor for the synthesis of phytochrome 1, has been prepared in enantiomerically pure form beginning with N-aminopyrrole 64 and the acetylenic acid 62b. The key step involved a 3,5-sigmatropic rearrangement of N-pyrrolo enamide 66b.