1221892-57-4Relevant articles and documents
N -aryl chromophore ligands for bright europium luminescence
Shavaleev, Nail M.,Eliseeva, Svetlana V.,Scopelliti, Rosario,Buenzli, Jean-Claude G.
experimental part, p. 3927 - 3936 (2010/06/14)
Sterically hindered N-aryl-benzimidazole pyridine-2-carboxylic acids (aryl = phenyl, 4-biphenyl, 2-naphthyl) readily form homoleptic, neutral, nine-coordinate europium complexes which display efficient sensitized luminescence in solid state and in dichloromethane solution with quantum yields reaching 59% and have monoexponential and nearly temperature-independent lifetimes as long as 2.7 ms. The ligand-centered absorption band with a maximum at 321-342 nm and intensity (50-56) - 103 M-1cm -1 ensures efficient harvesting of excitation light by the complexes. Variation of N-aryl chromophore enhances the ligand absorption at 250-350 nm without changing its triplet state energy which amounts to (19.2-21.3) × 103 cm-1. Photophysical properties of europium complexes benefit from adequate protection of the metal by the ligands against non-radiative deactivation and efficient ligand-to-metal energy transfer exceeding 70%. A correlation is observed between the sensitized luminescence quantum yields of europium and the ligand triplet state energy; in certain cases it points to the presence of a second-sphere quenching of EuIII by co-crystallized water in the solid state.
