1221966-90-0Relevant articles and documents
Stereoselective intramolecular cyclization of γ-allylbenzamide via π-allylpalladium complex catalyzed by Pd(0)
Pham, Van-Thoai,Joo, Jae-Eun,Lee, Kee-Young,Kim, Tai-Won,Mu, Yu,Ham, Won-Hun
experimental part, p. 2123 - 2131 (2010/04/26)
An efficient procedure for synthesizing oxazines was developed by the palladium(0)-catalyzed intramolecular cyclization of a benzamide through a π-allylpalladium (II) complex. Interestingly, the diastereoselectivity of oxazine ring formation was dominantly controlled by the bulkiness of various protecting groups on the secondary alcohols.