1222190-45-5Relevant articles and documents
Total Synthesis and Stereochemical Assignment of Sunshinamide and Its Anticancer Activity
Goswami, Rajib Kumar,Mondal, Joyanta,Sarkar, Ruma,Sen, Prosenjit
supporting information, (2020/02/15)
Total synthesis of cyclodepsipeptide sunshinamide has been achieved for the first time using a convergent approach. The key features of this synthesis comprise Crimmins acetate aldol, Shiina esterification, amide coupling, macrolactamization, and an Isub
Stereoselective total synthesis of (+)-polyrhacitide A
Yadav,Rajendar,Ganganna,Srihari
scheme or table, p. 2154 - 2156 (2010/06/13)
A facile stereoselective total synthesis of secondary metabolite (+)-polyrhacitide A is described. Stereoselective aldol reaction, Horner-Wardsworth-Emmons reaction, Evans acetal intramolecular oxa-Michael reaction and diastereoselective syn reduction reaction are the key steps involved in the target synthesis.