1223593-48-3Relevant articles and documents
Super silyl stereo-directing groups for complete 1,5-Syn and -anti stereoselectivities in the aldol reactions of β-siloxy methyl ketones with aldehydes
Yamaoka, Yousuke,Yamamoto, Hisashi
scheme or table, p. 5354 - 5356 (2010/07/04)
In this communication, we report that substrate-controlled 1,5-syn and -anti stereoinduction in the aldol reaction of β-tris(trialkylsilyl)siloxy methyl ketones can be achieved with high diastereoselectivities. Tris(trialkylsilyl)silyl groups are easily p