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122410-18-8

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122410-18-8 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 122410-18-8 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,2,2,4,1 and 0 respectively; the second part has 2 digits, 1 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 122410-18:
(8*1)+(7*2)+(6*2)+(5*4)+(4*1)+(3*0)+(2*1)+(1*8)=68
68 % 10 = 8
So 122410-18-8 is a valid CAS Registry Number.

122410-18-8Relevant articles and documents

The [2,3]-Wittig rearrangements of lithioalkyl allyl ethers exhibited different cis,trans selectivities than [2,3] shifts in their lithiomethyl analogues

Keiner,Bruckner

, p. 13417 - 13424 (1994)

The reductive lithiation of O,S-acetals 9a-d initiated [2,3]-Wittig rearrangements whose cis-trans-selectivity depended on whether lithiomethyl (→ cis) or lithioalkyl allyl ethers reacted (→ trans). It is suggested that these rearrangements proceed via mi

Regioselective Ni-Catalyzed Carboxylation of Allylic and Propargylic Alcohols with Carbon Dioxide

Chen, Yue-Gang,Shuai, Bin,Ma, Cong,Zhang, Xiu-Jie,Fang, Ping,Mei, Tian-Sheng

supporting information, p. 2969 - 2972 (2017/06/07)

An efficient Ni-catalyzed reductive carboxylation of allylic alcohols with CO2 has been successfully developed, providing linear β,γ-unsaturated carboxylic acids as the sole regioisomer with generally high E/Z stereoselectivity. In addition, the carboxylic acids can be generated from propargylic alcohols via hydrogenation to give allylic alcohol intermediates, followed by carboxylation. A preliminary mechanistic investigation suggests that the hydrogenation step is made possible by a Ni hydride intermediate produced by a hydrogen atom transfer from water.

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