122422-84-8

Basic information

• Product Name: <3R*,4S*,5R*,9S*>-3-methyl-4-(phenylsulphonyl)bicyclo<4.3.0>-2-nonene
• CAS NO: 122422-84-8
• Molecular Weight: 276.4
• Mol File: 122422-84-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: <3R*,4S*,5R*,9S*>-3-methyl-4-(phenylsulphonyl)bicyclo<4.3.0>-2-nonene(CAS DataBase Reference)
• NIST Chemistry Reference: <3R*,4S*,5R*,9S*>-3-methyl-4-(phenylsulphonyl)bicyclo<4.3.0>-2-nonene(122422-84-8)
• EPA Substance Registry System: <3R*,4S*,5R*,9S*>-3-methyl-4-(phenylsulphonyl)bicyclo<4.3.0>-2-nonene(122422-84-8)

Safety Data

• Hazardous Substances Data: 122422-84-8(Hazardous Substances Data)

Upstream product

• 132666-41-2 <2R*,5S*>-2,5-dihydro-2-methyl-5-<(4Z)-5-(phenylsulphinyl)-4-pentenyl>thiophene S,S-dioxide 
• 134692-53-8 (1Z,6E,8E)-1-(phenylsulphonyl)-1,6,8-decatriene 
• 134692-58-3 (6E,8E)-1-(phenylsulphonyl)-6,8-decadien-2-ol and (6Z,8E)-1-(phenylsulphonyl)-6,8-decadien-2-ol 
• 134692-57-2 2-<(5E,7E)-5,7-nonadienyloxy>tetrahydro-2H-pyran and 2-<(5Z,7E)-5,7-nonadienyloxy>tetrahydro-2H-pyran 
• 95540-68-4 (5E,7E)-5,7-nonadienal and (5Z,7E)-nonadienal 
• 64275-79-2 (5E,7E)-5,7-nonadien-1-ol and (5Z,7E)-5,7-nonadien-1-ol 
• 134692-56-1 2-<(7E)-6-benzoyloxy-5-(phenylsulphonyl)-7-nonenyloxy>tetrahydro-2H-pyran 
• 122422-82-6 2-<5-(phenylsulphonyl)pentyloxy>tetrahydro-2H-pyran 
• 116511-95-6 (benzenesulfonyl)methyllithium 
• 34626-51-2 5-bromopentan-1-ol 
• 111-29-5 1 ,5-pentanediol 
• 37935-47-0 2-(5-bromopentyloxy)tetrahydropyran 
• 122422-81-5 (1E,7E,9E)-1-(phenylsulphonyl)-1,7,9-undecatriene 
• 122422-80-4 (1E,6E,8E)-1-(phenylsulphonyl)-1,6,8-decatriene 

Downstream Products

• 122422-91-7 (3aR,5S,7aR)-4-Benzenesulfonyl-4,5-dimethyl-2,3,3a,4,5,7a-hexahydro-1H-indene 
• 122422-91-7 (3aR,5R,7aS)-4-Benzenesulfonyl-4,5-dimethyl-2,3,3a,4,5,7a-hexahydro-1H-indene 

Relevant articles and documents

Asymmetric intramolecular Diels-Alder reactions of sulfoximine-activated trienes

A series of N-substituted sulfoximidoyl-1,6,8-nonatrienes and 1,7,9-decatrienes were synthesized and subjected to thermal intramolecular Diels-Alder (IMDA) reactions to give diastereomeric mixtures of substituted bicyclo[4.3.0]nonanes and -[4.4.0]decanes. The reactions showed varying selectivities. Endo/exo selectivity was interpreted in terms of a combination of steric factors and the asynchronous nature of the cycloadditions. Diastereofacial selectivity could be rationalised by considering attack by the diene on the less hindered face of the conformationally extended vinylic sulfoximine dienophile.

INTRAMOLECULAR DIELS-ALDER REACTIONS OF SULPHONYL-SUBSTITUTED TRIENES

The synthesis and intramolecular Diels-Alder reactions of sulphonyl-substituted trienes 1 and 2 are described.The stereoselectivities of the cycloadditions are discussed, and some reactions of the bicyclic products are reported.