122590-90-3

Basic information

• Product Name: α-(difluoromethyl)-2-furanmethanol
• Synonyms: α-(difluoromethyl)-2-furanmethanol
• CAS NO: 122590-90-3
• Molecular Weight: 288.272
• Mol File: 122590-90-3.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: α-(difluoromethyl)-2-furanmethanol(CAS DataBase Reference)
• NIST Chemistry Reference: α-(difluoromethyl)-2-furanmethanol(122590-90-3)
• EPA Substance Registry System: α-(difluoromethyl)-2-furanmethanol(122590-90-3)

Safety Data

• Hazardous Substances Data: 122590-90-3(Hazardous Substances Data)

Upstream product

• 108-98-5 thiophenol 
• 101068-11-5 ethyl 2,2-difluoro-2-(phenylthio)acetate 
• 130409-81-3 ethyl (2,2-difluoro-2-phenylsulfinyl)acetate 
• 98-01-1 furfural 
• 873-55-2 sodium benzenesulfonate 
• 1535-67-7 difluoromethyl phenyl sulfide 
• 1535-65-5 difluoromethyl phenyl sulfone 

Relevant articles and documents

Preparation of 1-aryl-2,2-difluoro enol esters via dehydrosulfonylation of α-(phenylsulfonyl)difluoromethylated benzoates

1-Aryl-2,2-difluoro enol benzoates 4 has been prepared from α-(phenylsulfonyl)-difluoromethylated benzoates 3, which can be readily obtained from the reactions between simple aldehydes and PhSO2CF2H (or TMSCF2SO2/sub

Nucleophilic difluoro(phenylsulfonyl)methylation of carbonyls with PhSO2CF2H reagent in the presence of in situ generated substoichiometric amount of base Dedicated to Professor Iwao Ojima on the occasion of his receipt of the ACS Aw

The reactions between carbonyl compounds and PhSO2CF 2H using substoichiometric amount of base in situ generated from N(TMS)3 and catalytic amount of Me4NF have been investigated. It is found that both enolizabl

Process for nucleophilic fluoroalkylation of aldehydes

Aryl difluoromethyl sulfone adds to alkehydes under phase transfer conditions to give novel substituted alcohols of the general formula wherein R is an aryl, cycloaliphatic, sec- or tert-aliphatic, or heterocyclic group and Ar is an aryl group. The substituted alcohols of formula I are of particular utility as intermediates in the synthesis of a variety of useful end products. For example, the products of formula I may be utilized in desulfonylation reactions, oxidation reactions and fluorination reactions.