122594-00-7

Basic information

• Product Name: (3S,4aR,6R,8aR)-6-Methoxy-8a-methyl-1-oxo-3-pent-4-enyl-decahydro-naphthalene-2-carboxylic acid 4-methoxy-benzyl ester
• CAS NO: 122594-00-7
• Molecular Weight: 428.569
• Mol File: 122594-00-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (3S,4aR,6R,8aR)-6-Methoxy-8a-methyl-1-oxo-3-pent-4-enyl-decahydro-naphthalene-2-carboxylic acid 4-methoxy-benzyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (3S,4aR,6R,8aR)-6-Methoxy-8a-methyl-1-oxo-3-pent-4-enyl-decahydro-naphthalene-2-carboxylic acid 4-methoxy-benzyl ester(122594-00-7)
• EPA Substance Registry System: (3S,4aR,6R,8aR)-6-Methoxy-8a-methyl-1-oxo-3-pent-4-enyl-decahydro-naphthalene-2-carboxylic acid 4-methoxy-benzyl ester(122594-00-7)

Safety Data

• Hazardous Substances Data: 122594-00-7(Hazardous Substances Data)

Upstream product

• 32042-72-1 C₁₃H₂₂O₃ 
• 122593-98-0 (4aS,6S,8aS)-6-Methoxy-8a-methyl-4a,5,6,7,8,8a-hexahydro-4H-naphthalen-1-one 
• 122594-07-4 C₁₄H₂₄O₃ 
• 122593-99-1 (3S,4aR,6R,8aR)-6-Methoxy-8a-methyl-1-oxo-3-pent-4-enyl-decahydro-naphthalene-2-carboxylic acid methyl ester 
• 105-13-5 4-Methoxybenzyl alcohol 

Relevant articles and documents

Stereoselective Synthesis of the Tricyclic Skeleton of the Taxane Diterpenes. The First C-Silylation of a Ketone Enolate

The application of the intramolecular dioxenone photocycloaddition to the efficient synthesis of the tricyclic skeleton of the taxane diterpenes, with complete control of the relative stereochemical relationship between the two six-membered rings (A and C), is described.The first example of C-silylation of a ketone (cyclooctanone B-ring) enolate is reported, and the origins of this remarkable reactivity are discussed.