122617-23-6Relevant articles and documents
?-Facial Selectivity in the Diels-Alder Reaction of 5-Substituted 1,3-Cyclopentadienes
Ishida, Masaru,Aoyama, Takamichi,Beniya, Yasufumi,Yamabe, Shinichi,Kato, Shinzi,Inagaki, Satoshi
, p. 3430 - 3439 (1993)
Theoretical and experimental studies are presented about ?-facial selectivities in Diels-Alder reactions of 5-substituted cyclopentadienes (1).The HOMO and the NHOMO of 1 were readily predicted from the orbital mixing rule to be distorted to favor the syn