12266-58-9

Basic information

• Product Name: Nickel, bis[(2,3-h)-2-propenenitrile]-
• Synonyms: Nickel,bis(acrylonitrile)- (6CI,7CI,8CI); 2-Propenenitrile, nickel complex; Bis(acrylonitrile)nickel; Bis(acrylonitrile)nickel(0); Bis(h2-acrylonitrile)nickel; Diacrylonitrilenickel
• CAS NO: 12266-58-9
• Molecular Formula: C₆H₆N₂Ni
• Molecular Weight: 164.84
• Mol File: 12266-58-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Nickel, bis[(2,3-h)-2-propenenitrile]-(CAS DataBase Reference)
• NIST Chemistry Reference: Nickel, bis[(2,3-h)-2-propenenitrile]-(12266-58-9)
• EPA Substance Registry System: Nickel, bis[(2,3-h)-2-propenenitrile]-(12266-58-9)

Safety Data

• Hazard Codes: 3:
• Safety Statements: − and NOx. See also NITRILES and NICKEL COMPOUNDS." target="_blank">Confirmed Human Carcinogen. Ignites spontaneously in a
• Hazardous Substances Data: 12266-58-9(Hazardous Substances Data)

Upstream product

• 107-13-1 acrylonitrile 
• 13463-39-3 tetracarbonyl nickel 

Downstream Products

• 32146-31-9 (CH₂CHCN)2NiP(C₆H₅)3 
• 31666-48-5 NCCHCH₂Ni(P(OC₆H₄CH₃-o)3)2 

Relevant articles and documents

tmeda-Nickel-Komplexe IV. Synthese und Struktur von (tmeda)Ni(H2C=CHCOOCH3)2

Ni(C2H4)3, Ni(cdt), or Ni(cod)2 react with tmeda and acrylic acid methyl ester, methyl vinyl ether, and acrylonitrile in ether to afford (tmeda)Ni(H2C=CHCOOCH3)2 (3, orange-red crystals), (tmeda)Ni(H2C=CHCOCH3)2 (4, red crystals), and (tmeda)Ni(H2C=CHCN)2