1226636-13-0Relevant articles and documents
Rh(I)-Catalyzed olefin hydroarylation with electron-deficient perfluoroarenes
Sun, Zhong-Ming,Zhang, Jing,Manan, Rajith S.,Zhao, Pinjing
supporting information; experimental part, p. 6935 - 6937 (2010/08/06)
Assisted by a partially aqueous media, a catalyst system of [Rh(cod)(OH)]2 and DPPBenzene ligand effectively promotes direct conjugate additions by perfluoroarenes. This formal C-H alkylation process represents a rare example of olefin hydroarylation with electron-deficient arenes. The catalyst system can be modified to selectively form the corresponding olefination products under anhydrous conditions.