122778-23-8

Basic information

• Product Name: (1R,3R,4S)-p-menthan-3-yl hydrogen propylmalonate
• CAS NO: 122778-23-8
• Molecular Weight: 284.396
• Mol File: 122778-23-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1R,3R,4S)-p-menthan-3-yl hydrogen propylmalonate(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,3R,4S)-p-menthan-3-yl hydrogen propylmalonate(122778-23-8)
• EPA Substance Registry System: (1R,3R,4S)-p-menthan-3-yl hydrogen propylmalonate(122778-23-8)

Safety Data

• Hazardous Substances Data: 122778-23-8(Hazardous Substances Data)

Upstream product

• 2216-51-5 (-)-menthol 
• 616-62-6 n-propylmalonic acid 

Downstream Products

• 122778-47-6 (2S)-2-(dimethyl-t-butylsiloxymethyl)pentyl (S)-3,3,3-trifluoro-2-methoxy-2-phenylpropionate 
• 122872-34-8 (2S)-2-methylpentyl (S)-3,3,3-trifluoro-2-methoxy-2-phenylpropionate 
• 122778-42-1 (1R,3R,4S)-p-menthan-3-yl (2R)-2-(dimethyl-t-butylsiloxymethyl)valerate 
• 122778-50-1 (S)-2-Chloromethyl-pentanoic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester 
• 122778-51-2 (S)-2-Methyl-pentanoic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester 
• 105-30-6 (S)-2-methyl-1-pentanol 

Relevant articles and documents

Asymmetric Syntheses of Chiral Propane-1,3-diols Starting from Malonic Acid

Syntheses of chiral intermediates having one tertiary asymmetric centre were carried out via chiral half-esters of monoalkylmalonic acids.The menthyl half-ester of ethylmalonic acid afforded a single diastereoisomer through crystallisation-induced asymmetric transformation (second-order asymmertic transformation).Furthermore enantioselective preparation of unsymmertical propane-1,3-diol derivatives was achieved by the use of 8-phenylmenthyl half-esters.