1228107-73-0

Basic information

• Product Name: (5-benzyloxypent-3-ynyl)benzene
• Synonyms: (5-benzyloxypent-3-ynyl)benzene
• CAS NO: 1228107-73-0
• Molecular Weight: 250.34
• Mol File: 1228107-73-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (5-benzyloxypent-3-ynyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (5-benzyloxypent-3-ynyl)benzene(1228107-73-0)
• EPA Substance Registry System: (5-benzyloxypent-3-ynyl)benzene(1228107-73-0)

Safety Data

• Hazardous Substances Data: 1228107-73-0(Hazardous Substances Data)

Upstream product

• 100-39-0 benzyl bromide 

Downstream Products

• 40339-21-7 penta-3,4-dienyl-benzene 
• 81890-10-0 1-(1-deuterio-1,2-propadienyl)benzene 

Relevant articles and documents

Gold(I)-catalyzed rearrangement of propargyl benzyl ethers: A practical method for the generation and in situ transformation of substituted allenes

A series of benzyl propargyl ethers react with a gold(I) catalyst to furnish variously substituted allenes via a 1,5-hydride shift/fragmentation sequence. This transformation is rapid and practical. It can be performed under very mild conditions (room temperature or 60 °C) using terminal as well as substituted alkyne substrates bearing a primary, secondary, or tertiary benzyl ether group. The allenes thus formed can be reacted in situ with an internal or external nucleophile, corresponding to an overall reductive substitution process, to produce more functionalized compounds.