1228172-16-4Relevant articles and documents
Tunable bromomagnesium thiolate tishchenko reaction catalysts: Intermolecular aldehyde-trifluoromethylketone coupling
Cronin, Linda,Manoni, Francesco,O'Connor, Cornelius J.,Connon, Stephen J.
, p. 3045 - 3048 (2010)
(Figure Presented) Applied knowledge: A new thiolate-catalyzed Tishchenko reaction inspired by biochemical processes features exceptionally good control over the catalyst's steric/electronic properties. The isolation of reaction intermediates provided valua-ble insights into the reaction mechanism, which in turn has allowed the development of the first cross-Tishchenko coupling reactions between aldehydes and activated ketones (see example).
