122908-29-6

Basic information

• Product Name: trans-3,6-Dimethoxy-6-methyl-3-(4-methylphenyl)cyclohexa-1,4-diene
• CAS NO: 122908-29-6
• Molecular Weight: 244.334
• Mol File: 122908-29-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: trans-3,6-Dimethoxy-6-methyl-3-(4-methylphenyl)cyclohexa-1,4-diene(CAS DataBase Reference)
• NIST Chemistry Reference: trans-3,6-Dimethoxy-6-methyl-3-(4-methylphenyl)cyclohexa-1,4-diene(122908-29-6)
• EPA Substance Registry System: trans-3,6-Dimethoxy-6-methyl-3-(4-methylphenyl)cyclohexa-1,4-diene(122908-29-6)

Safety Data

• Hazardous Substances Data: 122908-29-6(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 613-33-2 (4,4'-dimethyl-1,1'-biphenyl) 

Relevant articles and documents

SYNTHESIS OF PHENYL SUBSTITUTED CYCLOHEXA-1,4-DIENES AND CYCLOHEXA-2,5-DIENONES BY ANODIC METHOXYLATION OF ALKYLBIPHENYLS

The anodic methoxylation of a series of alkylbiphenyls (2-, 3-, 4-methylbiphenyl, 3,3'-, 4,4'-dimethylbiphenyl, 4-ethylbiphenyl and 4,4'-di-tert-butylbiphenyl) carried out under constant current intensity afforded, in a process of two electrons, a number of cis/trans cyclohexa-1,4-dienes and, in a process of four electrons, a number of cyclohexa-2,5-dienones after acidic hydrolysis of the corresponding cyclohexa-1,4-diene ketals.In some cases, side-chain substitution products were also obtained.Probable mechanisms are proposed.