122924-26-9

Basic information

• Product Name: 3--2-cyclohexen-1-one
• Synonyms: 3--2-cyclohexen-1-one
• CAS NO: 122924-26-9
• Molecular Weight: 240.225
• Mol File: 122924-26-9.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: 3--2-cyclohexen-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 3--2-cyclohexen-1-one(122924-26-9)
• EPA Substance Registry System: 3--2-cyclohexen-1-one(122924-26-9)

Safety Data

• Hazardous Substances Data: 122924-26-9(Hazardous Substances Data)

Upstream product

• 5323-87-5 3-Ethoxycyclohex-2-en-1-one 
• 402-43-7 p-trifluoromethylphenyl bromide 
• 504-02-9 1,3-cylohexanedione 
• 930-68-7 cyclohexenone 
• 598-32-3 2-hydroxy-3-butene 
• 709-63-7 1-(4-trifluoromethylphenyl)ethanone 
• 60174-91-6 4′-(trifluoromethyl)-3,4-dihydro-[1,1′-biphenyl]-1(2H)-ol 
• 128796-39-4 4-trifluoromethylphenylboronic acid 
• 402-51-7 4-(trifluoromethyl)phenylmagnesium bromide 

Downstream Products

• 1092571-60-2 (R)-3-methyl-3-(4-(trifluoromethyl)phenyl)cyclohexan-1-one 
• 1004988-96-8 (S)-3-methyl-3-(4-(trifluoromethyl)phenyl)cyclohexan-1-one 
• 1199807-36-7 (S)-3-ethyl-3-(4-(trifluoromethyl)phenyl)cyclohexanone 
• 1251958-63-0 C₁₅H₁₇F₃O 
• 1613527-20-0 N-(3-(4-(trifluoromethyl)phenyl)cyclohex-2-enyl)acetamide 
• 1613527-40-4 N-(5-(4-(trifluoromethyl)phenyl)cyclohexa-1,5-dienyl)acetamide 
• 1601389-57-4 (S)-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-3-(4-(trifluoromethyl)phenyl)cyclohexan-1-one 
• 1453494-27-3 C₁₃H₁₂F₃NO 
• 400747-98-0 4'-(trifluoromethyl)-[1,1'-biphenyl]-3-amine 
• 365426-93-3 4'-(trifluoromethyl)-[1,1'-biphenyl]-3-ol 
• 1415503-54-6 4-allyl-4'-(trifluoromethyl)-5,6-dihydro-[1,1'-bi(phenyl)]-3(4H)-one 
• 122902-27-6 (5R,7S)-2,2-Dimethyl-7-(4-trifluoromethyl-phenyl)-1,3-dioxa-spiro[4.5]decane 
• 122902-27-6 (5R,7R)-2,2-Dimethyl-7-(4-trifluoromethyl-phenyl)-1,3-dioxa-spiro[4.5]decane 
• 122902-23-2 1-(Hydroxymethyl)-3-phenylcyclohexanol 

Relevant articles and documents

Palladium mediated one-pot synthesis of 3-aryl-cyclohexenones and 1,5-diketones from allyl alcohols and aryl ketones

One-pot synthesis of Robinson annulated 3-aryl-cyclohexenones from allyl alcohols and ketones using palladium is reported. Long chain aliphatic or aryl substitutions at the C1 position of allyl alcohol result in the formation of 1,5-diketone products. This simple one-pot method avoids the use of highly electrophilic vinyl ketones.

Highly enantioselective synthesis of chiral cyclic allylic amines via RH-catalyzed asymmetric hydrogenation

Highly regioselective and enantioselective asymmetric hydrogenation of cyclic dienamides catalyzed by an Rh-DuanPhos complex has been developed, which provides a readily accessible method for the synthesis of chiral cyclic allylic amines in excellent enantioselectivities (up to 99% ee). The products are valuable chiral building blocks and could be easily transformed to multisubstituted cyclohexane derivatives.

Aerobic oxidative heck/dehydrogenation reactions of cyclohexenones: Efficient access to meta-substituted phenols

Jockeying for the (meta)position: A new dicationic palladium(II) catalyst, employing a 6,6′-dimethyl-2,2′-bipyridine ligand, promotes both the aerobic oxidative Heck coupling and dehydrogenation reactions of cyclohexenones. These reactions may be combined in a one-pot sequence to enable the straightforward synthesis of meta-substituted phenols (see scheme). Copyright