122945-22-6Relevant articles and documents
Reactions of 2,5-Furandicarbaldehyde with Stabilized Phosphonium Ylides. Applications to the Synthesis of 5-Vinyl-2-furaldehyde and 2,5-Divinylfuran Derivatives
Dominguez, Carmen,Csaky, Aurelio G.,Magano, Javier,Plumet, Joaquin
, p. 172 - 175 (1989)
By simple modification of the molar proportion of reactants, it was possible to selectively functionalize an aldehyde group in 2,5-furandicarbaldehyde (1), by Wittig reaction with stabilized ylides 2.The scope of the procedure is extended to the preparati
Oxidation of 5-hydroxymethylfurfural an derivatives to furanaldahydes with 2,2,6,6-tetramethylpiperidine oxide radical-co-oxidant pairs
Cottier, Louis,Descotes, Gerard,Lewkowski, Jaroslaw,Skowronski, Romuald,Viollet, Estelle
, p. 927 - 930 (2007/10/03)
The oxidation of 5-hydroxymethylfurfural (1) or 5-hydroxymethylfurfurylideneacetophenone (4) with verious 4-substituted 2,2,6,6-tetramethylpiperidine radicals (TEMPO) 3a-d and supporting co-oxidants gave corresponding adehydes 2 or 5 in fair yields.