1229806-01-2

Basic information

• Product Name: (S)-4-(4-fluorophenyl)-5-methyl-5-nitrohexan-2-one
• Synonyms: (S)-4-(4-fluorophenyl)-5-methyl-5-nitrohexan-2-one
• CAS NO: 1229806-01-2
• Molecular Weight: 253.273
• Mol File: 1229806-01-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (S)-4-(4-fluorophenyl)-5-methyl-5-nitrohexan-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-4-(4-fluorophenyl)-5-methyl-5-nitrohexan-2-one(1229806-01-2)
• EPA Substance Registry System: (S)-4-(4-fluorophenyl)-5-methyl-5-nitrohexan-2-one(1229806-01-2)

Safety Data

• Hazardous Substances Data: 1229806-01-2(Hazardous Substances Data)

Upstream product

• 79-46-9 2-nitropropane 
• 65300-29-0 4-(4-fluorophenyl)but-3-en-2-one 

Relevant articles and documents

Camphor-derived C1-symmetric chiral diamine organocatalysts for asymmetric Michael addition of nitroalkanes to enones

A series of stable C1-symmetric chiral diamines (2a-2l) were conveniently synthesized by condensing exo-(-)-bornylamine or (+)-(1S,2S,5R)-menthylamine with various commercially available Cbz-protected amino acids. Among them, 2a can efficiently promote the Michael addition of nitroalkanes to a broad scope of enones with high yields (up to 96%) and excellent enantioselectivities (up to 98%) under mild conditions.