123100-51-6

Basic information

• Product Name: 12-(2-Bromo-benzyl)-12-aza-tricyclo[6.3.1.0^2,7]dodeca-2,4,6,10-tetraen-9-one
• CAS NO: 123100-51-6
• Molecular Weight: 340.219
• Mol File: 123100-51-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 12-(2-Bromo-benzyl)-12-aza-tricyclo[6.3.1.0^2,7]dodeca-2,4,6,10-tetraen-9-one(CAS DataBase Reference)
• NIST Chemistry Reference: 12-(2-Bromo-benzyl)-12-aza-tricyclo[6.3.1.0^2,7]dodeca-2,4,6,10-tetraen-9-one(123100-51-6)
• EPA Substance Registry System: 12-(2-Bromo-benzyl)-12-aza-tricyclo[6.3.1.0^2,7]dodeca-2,4,6,10-tetraen-9-one(123100-51-6)

Safety Data

• Hazardous Substances Data: 123100-51-6(Hazardous Substances Data)

Upstream product

• 3433-80-5 1-Bromo-2-bromomethyl-benzene 
• 123100-48-1 1-(2-bromobenzyl)-3-hydroxypyridin-1-ium bromide 
• 109-00-2 3-HYDROXYPYRIDINE 
• 114325-62-1 C₁₂H₁₀BrNO 
• 118-92-3 anthranilic acid 

Relevant articles and documents

Scope of Tandem Cycloaddition/Radical Cyclization Methodology

Tandem cycloaddition/radical cyclization is an effective strategy for the rapid assembly of a wide variety of ring systems.To set up the reagents for this sequence, it is necessary to include a potential radical site in one of the two cycloaddition partners, located at an appropriate distance from a new double bond that will be formed in the cycloaddition step.Examples in which the cycloaddition step is or and in which the radical cyclization creates 5-, 6-, or 7-membered rings are described.Examples of the tandem methodology carried out in a completely intramolecular mode are also described.