123126-44-3

Basic information

• Product Name: Benzoyl azide, 3,4,5-tris(dodecyloxy)-
• CAS NO: 123126-44-3
• Molecular Formula: C43H77N3O4
• Molecular Weight: 700.102
• Mol File: 123126-44-3.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Benzoyl azide, 3,4,5-tris(dodecyloxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoyl azide, 3,4,5-tris(dodecyloxy)-(123126-44-3)
• EPA Substance Registry System: Benzoyl azide, 3,4,5-tris(dodecyloxy)-(123126-44-3)

Safety Data

• Hazardous Substances Data: 123126-44-3(Hazardous Substances Data)

Upstream product

• 380441-58-7 3,4,5-tris(dodecyloxy)benzoic acid 2,5-dioxopyrrolidin-1-yl ester 
• 117241-31-3 3,4,5-tridodecyloxy benzoic acid 
• 99-24-1 methyl galloate 
• 143-15-7 1-dodecylbromide 
• 123126-39-6 methyl [3,4,5-tris(n-dodecan-1-yloxy)]benzoate 
• 117241-33-5 3,4,5-tris(dodecanyloxy)benzoyl chloride 
• 10157-76-3 dodecyl 4-methylbenzenesulphonate 

Downstream Products

• 151237-05-7 3,4,5-tris(dodec-1-yloxy)aniline 
• 1431839-80-3 C₄₇H₈₆N₂O₆ 
• 1431839-78-9 C₄₆H₈₄N₂O₆ 
• 123126-47-6 3,4,5-tridodecyloxyphenyl isocyanate 

Relevant articles and documents

Distance Matters: Biasing Mechanism, Transfer of Asymmetry, and Stereomutation in N-Annulated Perylene Bisimide Supramolecular Polymers

The synthesis of two series of N-annulated perylene bisimides (PBIs), compounds 1 and 2, is reported, and their self-assembling features are thoroughly investigated by a complete set of spectroscopic measurements and theoretical calculations. The study co

Two-component gelation and morphology-dependent conductivity of a naphthalene-diimide (NDI) π-system by orthogonal hydrogen bonding

The utility of an external structure-directing agent to induce orthogonal H-bonding-mediated programmed supramolecular-assembly and gelation of an n-type NDI chromophore is reported. Further, the effect of π-stacking and morphology on electrical conductivity of semiconducting NDI building blocks is revealed.

Complexation-induced unfolding of heterocyclic ureas. Simple foldamers equilibrate with multiply hydrogen-bonded sheetlike structures

The synthesis and conformational studies of heterocyclic ureas (amides) 1-7 and their concentration-dependent unfolding to form multiply hydrogen-bonded complexes are described. Ureas 1 and 7 were prepared by reacting 2-aminopyridine and aminonaphthyridine 25, respectively, with triphosgene and 4-(dimethylamino)-pyridine (DMAP). Amine 25, in turn, was synthesized by a Knorr condensation of 2,6-diaminopyridine and 4,6-nonanedione. Heterocyclic ureas 3, 4, and 16 were prepared by treating their corresponding amino precursors with butylisocyanate, whereas bisureido naphthyridines 6 and 17 were prepared by heating 2,7-diamino-1,8-naphthyridine (13) with butylisocyanate and 3,4,5-tridodecyloxyphenyl isocyanate, respectively. The hydrogen-bonding modules 2 and 5 were synthesized by reacting 13 and 2-amino-1,8-naphthyridine with valeric anhydride. X-ray crystallographic analyses were performed on ureas 1, 3, 16, and 17, indicating that these ureas are intramolecularly hydrogen-bonded in the solid state. Moreover, detailed 1H NMR solution studies of 1, 3, 4, 6, and 7 indicate that similar folded structures form in chloroform. In addition, naphthyridinylureas 3 and 7 unfold and dimerize by forming four hydrogen bonds at high concentrations, and ureas 1 and 4 unfold in the presence of their hydrogen-bonding complements, amides 2 and 5, to form Complexes with three and four hydrogen bonds, respectively. Likewise, the mixing of 6 and 7 results in a mutual unfolding and formation of a robust, sheetlike, sextuply hydrogen-bonded complex. The hydrogen-bonding modules described are useful building blocks for self-assembly, and the unfolding process represents a very primitive mimicry of the helix-to-sheet transition shown by peptides and potentially shown by the hypothetical naphthyridinylurea 8.