123201-60-5Relevant articles and documents
REACTIVITY PARAMETERS OF THE METAL ASSISTED 1,2-CLEAVAGE OF PENICILLINS
Alpegiani, Marco,Bodeschi, Angelo,Bissolino, Pierluigi,Visentin, Giuseppina,Zarini, Franco,et al.
, p. 617 - 628 (2007/10/02)
A straightforward and smooth conversion of penicillins into 1,2-secopenicillanates is described.The thiazolidine ring opening is brought about by the co-operative effect of strong non-nucleophilic bases and thiophilic heavy metal salts.The nature of the l