1232680-29-3Relevant articles and documents
Synthesis of SL0101 carbasugar analogues: Carbasugars via Pd-catalyzed cyclitolization and post-cyclitolization transformations
Shan, Mingde,Odoherty, George A.
supporting information; experimental part, p. 2986 - 2989 (2010/08/19)
A general approach to the stereoselective synthesis of 5a-carbasugars has been developed. The route mimics our palladium-catalyzed glycosylation/ postglycosylation approach to carbohydrates in that it also utilizes a highly regio- and stereospecific palladium-catalyzed allylation and postglycosylation reaction sequence for the installation of either d- or l-cyclitols. This cyclitolization/postcyclitolization sequence was used for the enantioselective synthesis of a cyclitol analogue of SL0101, its d-sugar enantiomer, as well as several acetylation pattern analogues.