1233344-67-6

Basic information

• Product Name: 2-([1',1''-biphenyl]-4'-yl)-1H-anthra[1,2-d]imidazole-6,11-dione
• Synonyms: 2-([1',1''-biphenyl]-4'-yl)-1H-anthra[1,2-d]imidazole-6,11-dione
• CAS NO: 1233344-67-6
• Molecular Weight: 400.436
• Mol File: 1233344-67-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-([1',1''-biphenyl]-4'-yl)-1H-anthra[1,2-d]imidazole-6,11-dione(CAS DataBase Reference)
• NIST Chemistry Reference: 2-([1',1''-biphenyl]-4'-yl)-1H-anthra[1,2-d]imidazole-6,11-dione(1233344-67-6)
• EPA Substance Registry System: 2-([1',1''-biphenyl]-4'-yl)-1H-anthra[1,2-d]imidazole-6,11-dione(1233344-67-6)

Safety Data

• Hazardous Substances Data: 1233344-67-6(Hazardous Substances Data)

Upstream product

• 1758-68-5 1,2-diamino-9,10-anthraquinone 
• 3218-36-8 4-Phenylbenzaldehyde 

Relevant articles and documents

Imidazoanthraquinone derivatives for the chromofluorogenic sensing of basic anions and trivalent metal cations

Four imidazoanthraquinone derivatives (2a-d) were synthesized and characterized and their coordination behavior against selected anions and cations tested. Acetonitrile solutions of probes showed charge-transfer absorptions in the 407-465 nm range. The four probes emitted in the 533-571 nm interval. The recognition ability of 2a-d was evaluated in the presence of F-, Cl-, Br-, I-, OCN-, BzO-, ClO4-, AcO-, HSO4-, H2PO4-, and CN-. Only F-, AcO-, and H2PO4- induced a new red-shifted absorption band that was attributed to a deprotonation process involving the amine moiety of the imidazole ring. Moreover, upon increasing quantities of F-, AcO-, and H2PO4-, moderate quenching was induced in the emission of 2a-d together with the appearance of a new red-shifted band. The UV-visible and emission behavior of the four probes in the presence of Cu2+, Co2+, Mg2+, Fe3+, Ba2+, Fe2+, Ni2+, Ca2+, Zn2+, Pb2+, Cd2+, Cr3+, Al3+, K+, and Li+ was also assessed. Only addition of Fe3+, Cr3+, and Al3+ caused a new blue-shifted band in 2a-d that was ascribed to a preferential coordination with the acceptor part of the probes. Moreover, an important quenching of the emission was observed which was ascribed to the interaction between these trivalent cations and 2a-d.